We have studied energy levels in 63Fe populated in the \beta -decay of 63Mn. A new (preliminary) level scheme of 63Fe includes 10 excited states connected by 21 \gamma -rays. The first excited states at 357 and 451 keV have the level half-lives of 110 ps and 780 ps, respectively. Three states, at 357, 451, and 1132 keV, are strongly \beta -fed with \mathop {\mathgroup \symoperators log}\nolimits ft \sim 5, while there is only a very week \beta -feeding, if any at all, to the ground state. The new results imply that 63Fe departs from a simple shell model structure observed for heavier N=37 isotones of 65Ni and 67Zn.
PACS numbers: 23.20.Lv, 21.10.Tg, 23.20.–g, 27.50.+e
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