Acta Physica Polonica B

Vol. 36, No. 5, May 2005, page 1823


A Continuous-Time Random-Walk Approach to the Cole--Davidson Dielectric Response of Dipolar Liquids

B. Szabat, K.M. Langner, B. Kloesgen, K. Weron

We show how the Cole--Davidson relaxation response, characteristic of alcoholic systems, can be derived within the framework of the continuous-time random walk (CTRW). Using the random-variable formalism, we indicate that the high-frequency power law of dielectric spectra is determined by the heavy-tailed distribution of quantities that provide the spatio-temporal coupling in the random-walk process. As an illustration, we present the dielectric permittivity spectra of several butanediol isomers.

PACS numbers: 02.50.Cw, 02.50.Ey, 77.22.Gm



 
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