Acta Physica Polonica B

Vol. 34, No. 7, July 2003, page 3751


Fluctuations and Local Structure in Two-Dimensional Lennard--Jones Liquid

A.C. Mitus, R. Orlik, A.Z. Patashinski, A. Patrykiejew, S. Sokolowski, O. Riefert

We quantify the concept of ensembles of atoms' fluctuations for 2D liquids close to and in the two-phase coexistence region, using a probabilistic method of local structure analysis. Two ensembles are studied: gas-like independent gaussian fluctuations (IGF) A.C. Mituœ, A.Z. Patashinski, A. Patrykiejew, S. Sokolowski,  Phys. Rev. B66, 184202 (2002) and a truly solid-like fluctuations (SF) characteristic for a two-dimensional (2D) triangular solid. For a 2D Lennard--Jones (LJ) system simulated using Monte Carlo and molecular dynamics methods those ensembles yield a statistically reliable description of local solid-like structures in the two-phase region. Both ensembles undergo a spectacular breakdown as the density changes. A hypothetical relation of this breakdown to the behaviour of the heat capacity in the two-phase region is proposed.

PACS numbers: 61.20.Ja, 64.70.Dv


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