In experiments performed at the GSI Fragment Separator and at the GANIL SISSI-LISE3 facility the decay of 45Fe has been investigated. Implantation events of 45Fe ions, stopped in silicon telescopes, were correlated with radioactive decay events. The decay energy spectra exhibit a peak of an average energy of (1.14 \pm 0.05) MeV. This observation, together with the non-observation of coincident \gamma or \beta events, represent clear evidence for the two-proton ground state decay of 45Fe. The average half-life of 45Fe, deduced from both experiments, is T1/2 = 3.8 +2.0-0.8 ms.
PACS numbers: 21.10.Tg, 23.50.+z, 29.30.Ep
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