Acta Physica Polonica B

Vol. 34, No. 2, February 2003, page 255


UBe13: Prototype of a Non-Fermi-Liquid Superconductor

N. Oeschler, F. Kromer, T. Tayama, K. Tenya, P. Gegenwart, G. Sparn, F. Steglich, M. Lang, G.R. Stewart

We review pronounced non-Fermi-liquid (NFL) effects in the low-temperature\ normal state of the heavy-fermion superconductor UBe13\ (Tc\approx 0.9 K). We argue that these NFL effects may presumably be related to short-range antiferromagnetic (AF) correlations which are manifested in the superconducting (SC) state by a ``line of thermodynamic anomalies'', B\ast (T), between T\approx 0.7 K (B=0) and B\approx 4 T\ (T \rightarrow 0). These anomalies are shown to mark the precursor of the lower of the two phase transitions (at Tc1\ and Tc2) in U1-xThxBe13, xc1\approx 0.019 < x<xc2  \approx 0.0455. For xc2 < x < xc < 0.07, a single SC transition is stated which due to thermal expansion, \alpha (T), and specific heat, C(T), measurements, coincides with this lower transition at Tc2. We discuss two possible scenarios both of which imply an intimate interrelation of superconductivity with the symmetry-broken state that forms below Tc2. Finally, we address two other lines of thermal expansion anomalies in the T--x phase diagram of U1-xThxBe13\ which show an only weak dependence on magnetic field: (i) A positive \alpha (T) peak, along with a C(T) peak, is found in pure UBe13\ at Tmax\approx 2 K. Upon Th doping, Tmax(x) is depressed linearly and vanishes close to the upper critical Th concentration xc2\ at which the two phase transitions merge to one. (ii) A negative anomaly in \alpha (T) develops for x>xc2 at Tmin. Tmin(x) increases by more than a factor of two when raising the Th content to x=0.1. Similar to previous results by Aliev et al. , [F.G. Aliev et al. ,  J. Phys.: Condens. Matter 8, 9807 (1995)], an almost temperature-independent non-linear susceptibility, \chi (3)(T), is found for U0.9Th0.1Be13, at striking variance to \chi (3)(T) for pure UBe13. The implications of this observation for the assignment of the valence state of Uranium at x=0 and x=0.1 are also addressed.

PACS numbers: 74.25.Bt, 74.70.Tx


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